![]() The main postulates of this theory are given below:ġ. To predict the shape of the covalent molecule, Gillespie and Nyholm developed a theory known as valence shell electron pair repulsion theory. Resonance in NO 2 – Valence shell electron pair repulsion (VSEPR) theory It is represented by a double-headed arrow (↔).Ģ. The real structure of the molecule or ion is a hybrid of these structures called a resonance hybrid. More than one such structure of the same molecule or Ion is called resonating structure. In the box below, complete the Lewis electron-dot diagram for the S2Cl2 molecule by drawing in all of the electron pairs.The phenomena in which a molecule or ion cannot be represented by a single structure but represented by more than one structure to explain its properties is called resonance. They give you a large box for you to draw your answer in, but try this on your own! AP Chemistry Exam 2017 - #1c In the box below, draw a Lewis electron-dot diagram (or diagrams) for the HCO3 − ion that is (are) consistent with the given information. The hydrogen atom is bonded to one of the oxygen atoms. Two of the carbon-to-oxygen bonds have the same length and the third carbon-to-oxygen bond is longer than the other two. The HCO3− ion has three carbon-to-oxygen bonds. These exams can be found on the College Board website. ![]() The following questions are pieces of free-response questions that were on previous AP Chemistry exams. Since there were 3 oxygen atoms with a -1 charge, the sum is -3, which is equal to the -3 charge of the polyatomic ion. Quick Tip: An easy way to check if you calculated formal charge correctly is if the sum of the formal charges = the charge of the ion. There should be 5+6+6+6+6+3 valence electrons, so 32 total.ĭraw Phosphorus in the center and 4 oxygen atoms surrounding it with single bonds and full octets: If anything, just check it if an element past element 14 is involved (because that is when you can break the octet rule). It is good to always check your calculation of formal charge since it is easy to miscount something. When do I check the formal charge of an atom? This tells you that sulfur has a formal charge of +1 when drawn in SCN- with that representation of electrons. ![]() Look at the image above at the SCN- ion to the left and the way they calculated formal charge:įor the sulfur atom, they took the number of valence electrons (6) and subtracted it by the total number of lone electrons (2) and single bonds with carbon (3 ). This might may not be the most technical but it's the easiest way to remember it! The easiest way to calculate the formal charge of an atom is to do (# of valence electrons - # of dots - # of dashes). The -1 charge indicates that there is one more electron, so there must be a total of 24 valence electrons represented in the LDS.ĭraw the central atom, which in this case, is nitrogen since there is only one nitrogen atom.ĭraw the 3 oxygen atoms surrounding nitrogen and three single bonds connecting them to nitrogen. But.NO3- is a polyatomic ion and there is a charge attached to the molecule as a whole. Since there are three oxygen atoms, we must account for each: 5+6+6+6 = 23. ![]() ![]() Recall some steps for this process that we discussed in the last study guide:Ĭount the number of valence electrons that the molecule has in total. Let's try drawing the lewis dot structure (LDS) of the polyatomic ion NO3. How do you know when a structure has resonance? This will make more sense as we take a look at several examples. However, resonance is all about representing a molecule in varying ways just to make it clear that the molecule is actually an average of those representations in space. A common misconception is that structures that have resonance are truly able to exist with different bond connections. ![]()
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![]() ![]() Yes, the University of Phoenix holds accreditation for many of its programs. to attract more students, but those campuses are being closed and the school is moving towards an online-only format. The school itself has been the center of controversies and lawsuits since 2000.Īt one point, UoPX opened satellite campuses across the U.S. It admits all applicants, but has been experiencing declining enrollment since 2010. UoPX is a private, for-profit school that is currently owned and managed by a private equity firm. The quality of the education in some of the degree programs has been found to be lacking by experts in relevant fields, and students may find their degree doesn’t deliver on the promise of getting a good job after graduation. The school offers degrees in areas of concentration that include: The level of defaults has dropped to 12.3% by 2019, but it was still one of the highest in the U.S. One of the indicators that UoPX has struggled over the years is demonstrated by the fact that the five-year student loan default rate was almost 50% in 2016. Since 2020, the university has seen new growth and improvements that have made it a force in online education once again. UoPX has had its troubles, but has also seen an upturn in the last half-decade. UoPX endured many scandals, rightly, for misleading advertising and shady business practices in the early 2000s. When looking at the student outcomes, graduation rate, university rankings, and reputation among employers, it’s hard to classify the University of Phoenix (UoPX). These include business, health sciences, information technology and education degrees among others. The university offers more than 100 undergraduate and graduate degree programs to its 500,000 students. The University of Phoenix is one of the largest online colleges in America. The University of Phoenix has been a pioneer in online learning since 1975. One of the largest online schools, they have a student body of over 500,000 students and offer degrees in business, health sciences, information technology, education and many other fields. The University of Phoenix is an online university that offers more than 100 undergraduate and graduate degree programs. The University of Phoenix is one of the most recognizable names in online higher education, but not always for the best reasons. 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![]() For example, if your custom JavaScript adds some random emojis to the end of the text, then you might want to enable this option. On your smartphone, visit and enter your caption or comment. It's useful for generating Instagram bio symbols to make your profile stand out and have a little bit of individuality. Here's a screenshot of an example question/answer and here's the example question text to copy/paste.ĭo you want the output text to wrap around when it reaches the end of the output box? Usually you do, but with some "multi-line" fonts, you don't.ĭo you want to show a "randomize" button for the output text box? This feature only makes sense if your font has "randomization" within its custom JavaScript code. Welcome This site allows you to generate text fonts that you can copy and paste into your Instagram bio. Step 2: You will land on a website that quickly changes. If you want a custom transformation, but don't know JavaScript, you could ask ChatGPT (or similar) to help by giving it the preceding instructions, and describing the functionality you want. Mark Zuckerberg has unveiled Threads, a clone of Twitter designed to lure people turned off by the social network’s changes under owner Elon Musk. How do you change the font on Instagram post Step 1: Search for Free Fonts Generator in the Google. Cursive, bold fonts with Instagram free font generator Or Tailwind. After typing the text in the box, a wide variety of options appears. Copy the result from the below and paste it insta bio box. ![]() Enter your regular bio or text into the input box. First of all, go to the Instagram Fonts Generator website. The function must be named "transform" and it should accept one input (text) and return the final output text. Try it out today and take your content to the next level with our user-friendly font generator FontGeneratorOnline allows you to generate text to fancy fonts where you can copy and paste into your social media bios also are known as (Instagram fonts or fancy fonts). Change font Instagram bio & Instagram captions to stand out. At Instagram Fonts, you can simply type the text you want to change into a cool, fun font. You do not need special skills to use this web application, anyone can use this tool very easily. You can define a custom JavaScript function in the box below that will be used to transform your final text after all your rules have been applied. ![]() ![]() Wash your green beans and dry them well with paper towels. For full instructions, including amounts and temperatures, see the recipe card below. This section shows how to make roasted green beans, with step-by-step photos and details about the technique, to help you visualize it. Shredded parmesan would be delicious, too. Grated Parmesan Cheese – You can buy pre-grated for convenience, or grate it yourself fresh for maximum flavor.Fresh garlic also tends to burn when roasting out in the open for very long, so I’ll show you below how I make these roasted garlic green beans without burning the garlic. Garlic – Yep, these garlicky green beans are definitely for all the garlic lovers… because we’re using a whole head of garlic in this recipe! That may seem like a lot, but when you slice it thinly and let it caramelize in the oven, it’s just perfect.Sea Salt & Black Pepper – You can adjust to taste, but I like 1/2 teaspoon sea salt and 1/4 teaspoon black pepper per pound of green beans.Feel free to skip it if this isn’t important to you. ![]()
![]() ![]() Caroline Polachek) Disc 1 12 Go Disc 1 13 Palaces (Feat. Credit: Frank Hoensch/Redferns Flume has seemingly confirmed his imminent return to the limelight, sharing an ambient new tune with a teaser video plainly labelled. Australian producer Flume has shared a new teaser video titled 2022, hinting at a collaboration with virtual band Gorillaz. Emma Louise) Disc 1 10 Love Light Disc 1 11 Sirens (Feat. Ahead of the producer’s third album release. Kucka) Disc 1 5 I Can't Tell (LAUREL) Disc 1 6 Get U Disc 1 7 Jasper's Song Disc 1 8 Only Fans (Feat. MAY-A) Disc 1 3 DHLC Disc 1 4 Flume & QUIET BISON - Escape (Feat. I recall them working on a music back in 2018 or 2019. of Discs: 1 disc(s) Studio / Label: Transgressive UK Release Date: View our feedback musicmagpieshop Disc Track Title Duration Disc 1 1 Highest Building (Feat. I swear the vocal is Damon Albarn So stoked just realised he's part of gorillaz, i feel terrible, but thats incredible It is. Release: 2022 Album: Flume - Palaces Release date: 5/20/22 Tracklist: 1 Highest Building (featuring Oklou) 3:36 2 Say Nothing (featuring May-a) 3:52 3 DHL. CD DVD Electronics Books Video Games Vinyl Flume : Palaces CD Album (Limited Edition) (2022) ***NEW*** Fast and FREE P & P Title: Palaces Artist: Flume Genre: Dance|Electro Format: CD / Album (Limited Edition) Type: CD No. ![]() i think he has a lot of unreleased stuff which he has worked on over the past two years, so i think it is safe to say that an. The album will be his third LP following his self-titled release in 2012 and ‘Skin’ which dropped. Possibly Australia’s largest electronic export Flume has announced his sophomore album ‘Palaces’ that will be due out May 20th. Palaces CD Album (Limited Edition) (2022). FLUME : PALACES CD Album (Limited Edition) (2022). FOR SALE Of Discs: 1 disc(s) Studio / Label: Transgressive UK Release Date: 17 295041349080. if he continues the three year pattern, we should be expecting an album in 2022. Flume announces album, shares new single ‘Say Nothing’ featuring MAY-A. FLUME : PALACES CD Album (Limited Edition) (2022) NEW Fast and FREE P & P - £12.36. Of Discs: 1 disc(s) Studio / Label: Transgressive UK Release Date. flume - came out towards the end of 2012 (almost 2013) skin - came out in 2016. Item: 295041349080 Flume : Palaces CD Album (Limited Edition) (2022) ***NEW*** Fast and FREE P & P. At the 2022 ARIA Music Awards, the album earned Flume a nomination for ARIA Award for Best Solo Artist and album was nominated for Best Dance/Electronic Release, Best Cover Art, Best Produced. Flume - Palaces Lyrics and Tracklist Genius Palaces Released Palaces Tracklist 1 Highest Building (Ft. ![]() ![]() ![]() On its own, it is a great OCR option for Mac but it lacks in power when compared to FineReader 12 for Windows. OverallįineReader Pro offers great features, strong recognition capabilities and the quality that you can expect from ABBY. The documents converted with FineReader can also be accessed using text-to-speech facilities and the software supports over 180 languages. FineReader’s advanced OCR features also include text orientation, layout retention and size/quality managing options. Then you can convert the document into the format that better suits your needs. You can take photos of a document with your device and apply FineReader’s image pre-processing tools to make corrections and adjustments to get a better text recognition. The advanced options allow you to use your mobile phone or digital camera as a scanner. It can recognize automatically document characteristics such as language or layout and also gives you the chance you to make manual adjustments. The tool combines automatic and manual functions for optimal results. Using FineReaderPro is simple and you will be able to start using it immediately without any hassle. You get guidance through every step of the reading and conversion of documents and many tasks only take a few clicks to be completed. Jut like other applications created by ABBYY, FineReader is distinguished for its easy to use interface that makes the process pretty straightforward. You can create documents in editable formats such as Word, PowerPoint, Excel or HTML. While this may not have been yet validated by independent tests, the truth is that the files converted with FineReader recreate the format of the original document with exactitude. ABBYY has tested the accuracy of its software and has rated it with an impressive 99.8%. FineReader Pro makes things simple and effective by offering a high level of precision for text recognition and keeping the exact layout of the document. The fact that FineReader Pro is an ABBYY product means that it has a great character recognition, which guarantees accurate results when extracting text to get an exact digital version form your paper documents. Here is what this OCR application offers for Mac users. While it is not as solid as the Windows counterpart, FineReader 12 Professional, FineReader Pro for Mac is a remarkable solution supported by ABBYY’s top technology. FineReader Pro for Mac offers greater accuracy and better performance than the Express Edition, the previous OS X compatible version of the software. Since the launch of the original FineReader in 1993, ABBYY has been working on improving the tool with every new release. Best Professional Outliner Software for Macs: The Top 5 Outliners Reviewed ![]() ![]() ![]() This means there may be some bugs where cum gets on your skirt instead of your panties, or lands on your shirt instead of your belly. Body and clothing condition was built primarily around the concept of external fluids getting on you, not your fluids coming out.If you notice an orgasm where you get soiled inappropriately (such as getting cum or femlube on you while in the pool), please let us know so we can fix it. Because we added calls to this code to so many locations, the possibility that we made a mistake in a given location is greater.(Vaginal wetness is chosen at character creation, but can be modified by several things during the course of the game, usually in the direction of 'more wet'.) Female wetness is determined primarily by the base vaginal wetness.These ejaculations will always take things like virility boosts and mutations into account. Small ejaculations from a predominantly female orgasm are only about 1/3rd the volume of a normal ejaculation. Semen ejaculation volume is retrieved from the standard formulas built into the fertility code. ![]() Arousal trimming mechanic has been added to cap arousal post orgasm, which should help reduce incidents of runaway arousal.Orgasming now reduces player energy by 2.Additional satisfaction and arousal reduction effects are provided for futa characters, due to the dual nature of their orgasm.Sometimes cum or femlube from orgasms are "clean" because you clean up afterward, or you were naked, etc.Pussy juice and cum possibilities are fed to the body condition system to make you and or your clothes wet in relevant location."Female" orgasms result in a small ejaculation, while "male" orgasms result in a full ejaculation.The primary purpose is adjusting the semen reserve and feeding the body condition system.This is code that is called with arguments for every orgasm in the game except for the sex system and prologue.New orgasm mechanic has been added to the game.Female chastity should still allow male masturbation, and vice versa.Overall appearance is nicer, and the disjointed text has been removed.Futa players are rewarded with a written scene for their masturbation.You will now see a window that explains the masturbation outcome-along with an orgasm image if successful-rather than just having a simple corner notification.Sufficiently pregnant women will get a new screen with a "how will this work" image when their belly is too big to make a masturbation session practical.Pregnancy now gets in the way of female masturbation options, and can reduce odds of success. ![]()
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